They were the last non-Spanish winners of the competition when they lifted the trophy in 2012/13.
Wednesday's opponents Bayern have been critics of the French side too.
Emery said that Neymar is fit and in the squad after missing last weekend's 0-0 draw away at Montpellier with a toe injury and that Angel Di Maria is in line to feature for the first time since he got injured during the last worldwide break.
'I'm looking forward to it, ' he said.
All eyes will undoubtedly be on the world's most expensive footballer for most of this season, and the game against Bayern Munich will be the same.
Midfielder-turned-right-back Joshua Kimmich will come up against him having replaced Philipp Lahm after the club legend's retirement. This should also be a high scoring game so I am also going to predict that the over 2.5 goals will win. "It gives me a lot of joy to see where football is now". This team is at home and have a better squad with the likes of Neymar.
So, he's hinted at a rotation system to keep both forwards happy.
Paris Saint-Germain are paying Neymar more than £600 000 per week according to leaked documents shown in German publication Der Spiegel.
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Last week, the French club's star forwards argued over who should take a penalty kick in the 79th minute against Lyon.
"He is absolutely right that money doesn't score goals but it does allow you to buy players who score goals", Hummels told reporters at the Parc des Princes.
Unai Emery is likely to set his Paris Saint-Germain side up in a 4-3-3. "Many of them also want to". Or maybe he refused to celebrate along with Neymar and Dani Alves?
He may be tempted to switch his usual style to keep PSG quiet.
Argentine winger Angel Di Maria also returns to the PSG squad after almost three weeks out injured.
The two are level on points after defeating Celtic and RSC Anderlecht in the first round of fixtures two weeks ago, and a victory for either side would put them in the driving seat as they bid to win the group.
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